Step 1: Define primary versus secondary pollutants. A primary pollutant is released straight from a source, while a secondary pollutant forms afterward through chemical reactions in the atmosphere. Step 2: Check each option against this rule. Carbon monoxide, sulphur dioxide and lead are all emitted directly from combustion or industrial sources, making them primary pollutants. Step 3: Explain tropospheric ozone. Ozone near the ground is not emitted directly. It forms when nitrogen oxides and volatile organic compounds react together under sunlight, which is the classic definition of a secondary pollutant. \[ \boxed{\text{Ozone (tropospheric)}} \]