Question:easy

Which of the following hydrocarbons has stronger London dispersion forces ?

Show Hint

London dispersion forces grow with the surface area and number of electrons, so a long unbranched chain beats a compact one.
Updated On: Oct 1, 2026
  • Methane
  • Ethane
  • n-pentane
  • neo-pentane
Show Solution

The Correct Option is C

Solution and Explanation

Step 1: Two factors
Dispersion strength depends on polarisability (more electrons, more polarisable) and shape (more surface contact means stronger attraction).

Step 2: Eliminate
Methane and ethane have far fewer electrons than a five-carbon alkane, so they are weaker.

Step 3: Choose between the isomers
Both pentanes have the same electrons. The linear n-pentane packs side by side with a large contact area, whereas branching makes neopentane compact and reduces the contact.

Step 4: Evidence
Boiling points: n-pentane 309 K, neopentane 283 K. The higher boiling point matches stronger forces in n-pentane.

Final Answer:
n-Pentane has the strongest dispersion forces. This is option (C). \[ \boxed{\text{(C) }\text{n-Pentane}} \]
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