Question:medium

Which of the following gases will have the highest rate of diffusion at the same temperature and pressure?

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Graham’s law of diffusion states that lighter gases (with lower molar masses) diffuse faster than heavier gases at the same temperature and pressure.
Updated On: Nov 26, 2025
  • \( \text{H}_2 \)
  • \( \text{O}_2 \)
  • \( \text{N}_2 \)
  • \( \text{CO}_2 \)
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The Correct Option is A

Solution and Explanation

Step 1: Grasp Graham's Law of Diffusion.

Graham's law states that a gas's diffusion rate is inversely proportional to the square root of its molar mass:

\[
\text{Rate} \propto \frac{1}{\sqrt{M}}
\]
where \( M \) represents the gas's molar mass.

Step 2: Contrast the molar masses of the gases.

- \( \text{H}_2 \) molar mass: \( 2 \, \text{g/mol} \).
- \( \text{O}_2 \) molar mass: \( 32 \, \text{g/mol} \).
- \( \text{N}_2 \) molar mass: \( 28 \, \text{g/mol} \).
- \( \text{CO}_2 \) molar mass: \( 44 \, \text{g/mol} \).

Step 3: Ascertain the diffusion rate.

Given that the diffusion rate is inversely proportional to the square root of the molar mass, the gas with the smallest molar mass will diffuse most rapidly.

Of the listed gases, \( \text{H}_2 \) possesses the lowest molar mass, thus exhibiting the highest diffusion rate.

Answer: Consequently, \( \text{H}_2 \) will exhibit the highest diffusion rate.
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