Question:medium

Which of the following compounds can not form iodoform?

Show Hint

Look for CH3CO- or CH3CH(OH)-; isobutyl alcohol is a primary alcohol with neither.
Updated On: Oct 1, 2026
  • Ethyl methyl ketone
  • Isopropyl alcohol
  • 3-Methyl - 2- butanone
  • Isobutyl alcohol
Show Solution

The Correct Option is D

Solution and Explanation

Step 1: Idea:
Test for the structural unit that leads to the $\text{CI}_3\text{-C=O}$ intermediate.

Step 2: Result:
Options A, B and C each have the methyl-carbonyl or methyl-carbinol unit. Isobutyl alcohol has $\text{-CH}_2\text{OH}$ at the end of a branched chain. Oxidation gives an aldehyde with no $\text{CH}_3\text{CO-}$ group.

Final Answer:
Isobutyl alcohol cannot form iodoform, option (D). \[ \boxed{\text{Isobutyl alcohol}} \]
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