Step 1: Skeletal maturation of the wrist is assessed by watching the order in which carpal ossification centres appear on radiographs.
Step 2: Ossification begins centrally in the wrist. The capitate, lying in the centre of the distal carpal row, is the very first to develop a bony centre during infancy.
Step 3: Reading outward in time after the capitate: hamate, then triquetrum, lunate, the scaphoid-trapezoid pair, trapezium, and finally the pisiform near puberty.
Step 4: Since trapezium, lunate and pisiform all appear much later, only the capitate satisfies being earliest.
\[\boxed{\text{Capitate}}\]