Step 1: Ways to Coagulate a Sol
A sol is coagulated by adding an electrolyte, by mixing oppositely charged sols, by electrophoresis, or by boiling.
Step 2: Apply to the Options
Electrophoresis, mixing oppositely charged sols and boiling are all in this list.
Step 3: Compare the options
Adding excess solvent merely dilutes the sol, so it is the one that does not cause coagulation.
Final Answer:
Only adding excess solvent fails to coagulate the sol.
\[ \boxed{\text{(B) }\text{by adding excess solvent}} \]