Step 1: Recall the trend.
Going down Group 17, the halogens change from gas to liquid to solid as the molecules get bigger and the forces between them grow.
Step 2: Place each.
Fluorine and chlorine are gases, iodine and astatine are solids. Bromine sits in between.
Step 3: Pick.
Bromine is the liquid at room temperature.
\[ \boxed{\text{Bromine, option 3}} \]