The question asks which of the given metals exhibits a body-centered cubic (BCC) crystal structure. Let's analyze the options:
Iron ($\alpha$-Fe): Iron is known to have an allotropic form known as $\alpha$-Iron (ferrite), which has a BCC structure at room temperature and up to 912°C.
Copper: Copper has a face-centered cubic (FCC) structure. This is not a BCC structure, so copper is not the correct answer.
Aluminum: Like copper, aluminum also has a face-centered cubic (FCC) structure, not a BCC structure.
Nickel: Nickel also crystallizes in a face-centered cubic (FCC) structure, similar to copper and aluminum.
The correct answer is Iron ($\alpha$-Fe) because it exhibits a body-centered cubic (BCC) structure.