Question:easy

Which among the following molecule exhibits paramagnetism?

Show Hint

A molecule is paramagnetic if it has an unpaired electron in its molecular orbitals; draw the MO configuration.
Updated On: Oct 1, 2026
  • \(\text{O}_2\)
  • \(\text{O}_3\)
  • \(\text{N}_2\)
  • \(\text{F}_2\)
Show Solution

The Correct Option is A

Solution and Explanation

Step 1: Quick Count:
Count the electrons in the $\pi^*$ level. O$_2$ has 16 electrons in total, so two electrons go into the two empty-looking $\pi^*$ orbitals, one each.

Step 2: Bond Order:
Bond order $= (10-6)/2 = 2$, and the molecule has a double bond with two parallel spins. That is why liquid oxygen is attracted by a magnet.

Step 3: Others:
N$_2$ has 14 electrons and F$_2$ has 18 electrons, in both cases every MO is full or empty. O$_3$ has no unpaired electron either. So (A).

Final Answer:
Option (A), O$_2$, is paramagnetic. \[ \boxed{\text{(A) } \text{O}_2} \]
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