Clinical pearl: in the fetus the placenta does the breathing, so the vessel closest to the placental return carries the highest oxygen. Oxygen-rich blood exits the placenta via the umbilical vein, bypasses the liver through the ductus venosus, and dumps straight into the inferior vena cava. That makes the IVC the most oxygenated large vessel, so option (b) is correct.
Eliminate the rest quickly: the SVC carries used blood back from the brain and arms, so it is poorly oxygenated. The right ventricle gets a blend that already includes SVC blood. The aorta is fed downstream after mixing across the ductus arteriosus, lowering its saturation further. Highest oxygen content tracks the IVC because it sits right at the receiving end of the umbilical/ductus venosus stream.
Ref: Nelson Textbook of Pediatrics, 20e.