Step 1: Formula.
\[ \Delta T_b = K_b\, m \]
Step 2: Find the molality.
Moles of solute are $3.00/250 = 0.012$, and in 0.100 kg of solvent the molality is 0.12.
Step 3: Multiply.
\[ \Delta T_b = 5.00 \times 0.12 = 0.60 \text{ K} \]
Step 4: Answer.
\[ \boxed{0.60 \text{ K}} \]