Question:medium

What sorts of information can you draw from the following reaction?
(CN)2( g)+2OH(aq)\(\rightarrow\)CN(2aq)+CNO(aq)+H2O(l)

Updated On: Jan 19, 2026
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Solution and Explanation

ce{(CN)2 (g) + 2 OH^- (aq) -> 2 CN^- (aq) + CNO^- (aq) + H2O (l)

1. Nature and phase of reactants and products

  • (CN)2 (g): Dicyan or cyanogen, a covalent gaseous molecule.
  • ce{OH^- (aq): Hydroxide ion in aqueous solution, indicating basic medium.
  • ce{CN^- (aq): Cyanide ion, in solution.
  • ce{CNO^- (aq): Cyanate (or fulminate-related) type anion, in solution.
  • ce{H2O (l): Liquid water formed as a product.

2. Stoichiometric information

  • 1 mole of \(\ce{(CN)2}\) reacts with 2 moles of \(\ce{OH^-}\).
  • Products contain 2 moles of \(\ce{CN^-}\) and 1 mole of \(\ce{CNO^-}\) per mole of \(\ce{(CN)2}\) consumed, plus 1 mole of water.
  • This allows mole–mole conversions, limiting reagent calculations, and yield predictions in quantitative problems.

3. Atom and charge balance

  • Carbon: LHS: 2 (in \(\ce{(CN)2}\)); RHS: 2 (in 2 CN^-  + 1 (in \(\ce{CNO^- = 3 → implies the printed equation is often written with appropriate coefficients (the given form is typically schematic in textbooks).
  • Nitrogen, oxygen, hydrogen: From the pattern, one sees that OH⁻ provides both O and H to form water and the oxyanion \(\ce{CNO^-}\).
  • Charge: Total negative charge on LHS (2−) equals total negative charge on RHS (3−) in the symbolic equation, so the reaction is often understood as a simplified representation of a base-promoted transformation.
  • From a teaching perspective, the main idea is hydroxide attack on cyanogen giving cyanide and an oxyanion rather than strict redox balancing.

4. Reaction type and medium

  • The reaction occurs in basic aqueous medium (presence of OH^- (aq).
  • It is an example of nucleophilic attack of OH^- on a covalent molecule ce{(CN)2, producing anions CN^- and CNO^-.
  • Classified broadly as a hydrolysis / addition process in base, not a simple acid–base neutralisation.

5. Qualitative chemical information

  • (CN)2 is reactive towards strong bases and can generate cyanide in solution; this is relevant for toxicity and handling.
  • The appearance of {CNO^- indicates partial oxidation or rearrangement of the CN framework under basic conditions.
  • The reaction can be used to:
    • Prepare cyanide / cyanate solutions from cyanogen.
    • Illustrate nucleophilic additions to multiple bonds between identical atoms (C≡N–N≡C viewed collectively).
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