Step 1: Method:
Use the proportion: 1 mol of water weighs 18 g, so 0.25 mol weighs one quarter of that.
Step 2: Working:
$0.25 = \tfrac14$, so $18 \div 4 = 4.5$ g.
Step 3: Eliminate:
18 g is a whole mole. 0.25 g and 5.4 g do not match 18 g times 0.25. Only 4.5 g fits, option (A).
Final Answer:
The mass is 4.5 g, option (A).
\[ \boxed{\text{(A) } 4.5\ \text{g}} \]