To determine the quantity of a 45\% acid solution needed to mix with a 20\% acid solution to get 800\ \text{mL} of a 29.875\% acid solution, we can use the concept of weighted averages or a simple algebraic equation. Here is a step-by-step solution:
Therefore, 316\ \text{mL} of the 45\% solution should be mixed with the 20\% solution to achieve the desired concentration. Thus, the correct answer is 316.