Question:medium

What product is formed when a ketone reacts with hydrazine (\( \text{NH}_2\text{NH}_2 \))?

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Aldehydes and ketones react with hydrazine to form hydrazones through condensation reactions involving the carbonyl group.
Updated On: Apr 16, 2026
  • Hydrazone
  • Alcohol
  • Ester
  • Carboxylic acid
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The Correct Option is A

Solution and Explanation

To determine the product formed when a ketone reacts with hydrazine (\( \text{NH}_2\text{NH}_2 \)), we need to understand the underlying chemical reaction that takes place.

  1. A ketone generally contains a carbonyl group (\( \text{C}= \text{O} \)). When it reacts with hydrazine, the reaction involves the nucleophilic attack by the nitrogen atom of hydrazine on the carbon atom of the carbonyl group.
  2. This reaction leads to the formation of an intermediate, followed by the removal of water (a condensation reaction).
  3. The final product formed from this reaction is a hydrazone. The general reaction can be represented as follows: \(\text{R}_2 \text{C}=\text{O} + \text{NH}_2\text{NH}_2 \rightarrow \text{R}_2 \text{C}=\text{NNH}_2 + \text{H}_2\text{O}\)where \( \text{R}_2 \text{C}=\text{O} \) represents a generic ketone.

Let's evaluate the given options:

  • Hydrazone: This is the correct answer. As explained, the reaction of a ketone with hydrazine results in the formation of a hydrazone.
  • Alcohol: This is incorrect. Alcohols are typically formed by the reduction of carbonyl groups or through other reactions, not through the reaction with hydrazine.
  • Ester: This is incorrect. Esters are formed in reactions typically involving an acid and an alcohol.
  • Carboxylic acid: This is incorrect. Carboxylic acids are not formed from ketones and hydrazine reactions; they require oxidation processes or other specific reactions.

Therefore, when a ketone reacts with hydrazine (\( \text{NH}_2\text{NH}_2 \)), the product formed is a hydrazone.

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