Question:medium

What is the oxidation number of oxygen in \(\text{KO}_2\) ?

Show Hint

KO2 is a superoxide with the O2 minus ion.
Updated On: Oct 1, 2026
  • \(-2\)
  • \(-1/2\)
  • \(-1\)
  • \(+2\)
Show Solution

The Correct Option is B

Solution and Explanation

Step 1: Identify the anion:
$\text{KO}_2$ is made of $\text{K}^+$ and $\text{O}_2^-$ (superoxide).

Step 2: Share the charge:
The two oxygen atoms together carry $-1$, so each carries $-1/2$.

Step 3: Compare:
Oxide $\text{O}^{2-}$ gives $-2$ and peroxide $\text{O}_2^{2-}$ gives $-1$, so the superoxide gives $-1/2$, option (B).

Final Answer:
Oxygen in KO2 is at -1/2. \[ \boxed{\text{(B) }-\tfrac{1}{2}} \]
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