What is the excess pressure inside a bubble of soap solution of radius 5.00 mm, given that the surface tension of soap solution at the temperature (20 °C) is 2.50 × 10–2 N m–1 ? If an air bubble of the same dimension were formed at depth of 40.0 cm inside a container containing the soap solution (of relative density 1.20), what would be the pressure inside the bubble ? (1 atmospheric pressure is 1.01 × 105 Pa).
A soap bubble in air has two liquid surfaces (inner and outer), so the excess pressure inside it is \( \Delta P_{\text{soap}} = \dfrac{4T}{r} \).
\( \Delta P_{\text{soap}} = \dfrac{4 \times 2.50 \times 10^{-2}}{5.00 \times 10^{-3}} \) \( = \dfrac{10.0 \times 10^{-2}}{5.00 \times 10^{-3}} = 20 \,\text{Pa} \)
Excess pressure inside the soap bubble = \( 20 \,\text{Pa} \).
An air bubble inside a liquid has only one liquid surface, so its excess pressure is \( \Delta P_{\text{air}} = \dfrac{2T}{r} \).
\( \Delta P_{\text{air}} = \dfrac{2 \times 2.50 \times 10^{-2}}{5.00 \times 10^{-3}} \) \( = \dfrac{5.0 \times 10^{-2}}{5.00 \times 10^{-3}} = 10 \,\text{Pa} \)
The hydrostatic pressure at depth \( h \) in the soap solution is \( P_{\text{hydro}} = \rho g h = 1200 \times 9.8 \times 0.40 \,\text{Pa} \).
\( P_{\text{hydro}} = 1200 \times 9.8 \times 0.40 \approx 4704 \,\text{Pa} \)
Total pressure just outside the air bubble at depth \( h \) is \( P_{\text{out}} = P_{\text{atm}} + P_{\text{hydro}} \).
\( P_{\text{out}} = 1.01 \times 10^{5} + 4704 \approx 1.057 \times 10^{5} \,\text{Pa} \)
Pressure inside the bubble will be this outside pressure plus excess pressure \( \Delta P_{\text{air}} \).
\( P_{\text{in}} = P_{\text{out}} + \Delta P_{\text{air}} \approx 1.057 \times 10^{5} + 10 \approx 1.0571 \times 10^{5} \,\text{Pa} \)
Pressure inside the air bubble at 40 cm depth \( \approx 1.06 \times 10^{5} \,\text{Pa} \).