Group 16 elements (like Sulphur) have a maximum possible oxidation state of +6, which corresponds to the total number of valence electrons they possess in their outermost shell.
Step 1: Understanding the Concept:
The sum of oxidation numbers in a neutral molecule must be zero. Oxygen typically has an oxidation number of $-2$. Step 2: Formula Application:
Let the oxidation number of sulphur be $x$.
$x + 3(-2) = 0$. Step 3: Explanation:
$x - 6 = 0 \implies x = +6$.
Sulphur is in its highest oxidation state in $SO_3$. Step 4: Final Answer:
The oxidation number of sulphur is +6.