Question:medium

What are X and Y respectively in the following set of reactions?

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Balz-Schiemann reaction is the standard method for synthesizing aryl fluorides from diazonium salts.
Updated On: Jun 3, 2026
  • KCl; KF
  • HCl; KF
  • HCl; (i) $HBF_{4}$ (ii) $\Delta$
  • Cu | HCl; (i) $HBF_{4}$ (ii) $\Delta$
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The Correct Option is C

Solution and Explanation

Step 1: Identify the reaction theme.
This is about turning aniline into a diazonium salt and then into fluorobenzene. The fluorine step uses the Balz-Schiemann reaction.

Step 2: Find reagent X.
Aniline is first changed into benzenediazonium chloride. This needs nitrous acid in hydrochloric acid, so X is HCl based diazotization, giving the diazonium chloride.

Step 3: Recall the fluorine introduction.
To put a fluorine onto the ring, we cannot just use a simple fluoride. We use the special Balz-Schiemann route.

Step 4: Find reagent Y.
The diazonium salt reacts with fluoroboric acid $HBF_4$ to make a stable salt, which is then heated. So Y is first $HBF_4$ and then heat $\Delta$.

Step 5: See the product.
On heating, the salt breaks down to give fluorobenzene, releasing nitrogen and boron trifluoride.

Step 6: State the answer.
So X is HCl and Y is first $HBF_4$ then $\Delta$. \[ \boxed{X = HCl,\ Y = (i)\,HBF_4\ (ii)\,\Delta} \]
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