Question:medium

What are X and Y in the following set of reactions?


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$KMnO_{4}$ converts alkyl groups on benzene rings to carboxylic acids.
Updated On: Jun 3, 2026
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The Correct Option is A

Solution and Explanation

Step 1: Identify the starting reactions.
This sequence works on toluene, first by an electrophilic substitution and then by oxidation of the methyl side chain.

Step 2: Do the substitution.
Toluene undergoes bromination on the ring. The methyl group directs the bromine to the ortho and para positions, giving a bromo-toluene.

Step 3: Oxidise the side chain.
Strong oxidation with $KMnO_4$ changes the methyl group into a carboxylic acid group. So the methyl becomes COOH.

Step 4: Build the product.
After bromination and then oxidation, we get a bromo-benzoic acid with the correct position of the groups.

Step 5: Match to the options.
Comparing the expected positions of the bromine and the acid group, the structure shown in option 1 is the right product arrangement.

Step 6: State the answer.
So the correct products X and Y are those in structure 1. \[ \boxed{\text{Structure 1}} \]
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