\(2.24 \ lit.\)
\(1.12\ lit.\)
\(0.84\ lit.\)
\(0.56\ lit.\)
To solve this problem, we can follow these steps:
BaCO_3 \rightarrow BaO + CO_2
Ba: 137 \ g/mol, \ C: 12 \ g/mol, \ O: 16 \times 3 = 48 \ g/mol
\text{Molar mass of } BaCO_3 = 137 + 12 + 48 = 197 \ g/mol
\text{Number of moles} = \frac{9.85 \, \text{g}}{197 \, \text{g/mol}} \approx 0.05 \, \text{moles}
0.05 \, \text{moles} \times 22.4 \, \text{lit/mole} = 1.12 \, \text{liters}
Thus, the volume of CO_2 obtained by the complete decomposition of 9.85 \, \text{gm} \, BaCO_3 is 1.12 \, \liters.
The correct answer is 1.12 \, \liters.