Step 1: Understand the condition.
Two rods of lengths $L_1$ and $L_2$ expand by different amounts when heated, yet the gap $(L_2 - L_1)$ must stay fixed at every temperature. We need the relation this forces between their lengths and expansion coefficients.
Step 2: Write the expansion of each rod.
For a temperature rise $\Delta T$, the increase in length is $\Delta L = L\alpha\,\Delta T$, so $$\Delta L_1 = L_1\alpha_1\,\Delta T,\qquad \Delta L_2 = L_2\alpha_2\,\Delta T.$$
Step 3: Translate the constancy condition.
If $(L_2 - L_1)$ never changes, then its change must be zero: $$\Delta L_2 - \Delta L_1 = 0.$$
Step 4: Set the expansions equal.
This means both rods must lengthen by the same amount: $$\Delta L_1 = \Delta L_2.$$
Step 5: Substitute the expressions.
$$L_1\alpha_1\,\Delta T = L_2\alpha_2\,\Delta T.$$
Step 6: Cancel the common factor.
Since $\Delta T$ is the same and non-zero for both, dividing it out gives $$L_1\alpha_1 = L_2\alpha_2.$$
\[ \boxed{L_1\alpha_1 = L_2\alpha_2} \]