Question:medium

Total number of electrons involved in the formation of bridge bonds in the structure of diborane is

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Diborane has 2 bridge bonds. Each banana bond requires exactly 2 electrons, making it 4 electrons in total for bridging.
Updated On: Jun 3, 2026
  • 6
  • 2
  • 4
  • 3
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The Correct Option is C

Solution and Explanation

Step 1: Recall the structure of diborane.
Diborane is $B_2H_6$. It has two kinds of bonds. Four hydrogens are normal terminal bonds and two hydrogens form special bridge bonds between the two boron atoms.

Step 2: Understand the bridge bond.
A bridge bond is a three-centre two-electron bond. This means three atoms, $B-H-B$, share just one pair of electrons. It is also called a banana bond.

Step 3: Count the bridge bonds.
In diborane there are exactly two of these $B-H-B$ bridge bonds.

Step 4: Count electrons per bridge.
Each three-centre bridge bond holds one pair, which is 2 electrons.

Step 5: Find the total.
Multiply the number of bridges by electrons per bridge. \[ 2 \text{ bridges} \times 2 \text{ electrons} = 4 \text{ electrons} \]

Step 6: State the answer.
So the total number of electrons in the bridge bonds is 4. \[ \boxed{4} \]
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