Step 1: Recall the fixed volume ratio between a sphere and its snug cylinder.
A sphere that fits exactly inside a cylinder (same radius, height equal to diameter) always occupies $\frac{2}{3}$ of that cylinder's volume, this is a standard geometric fact.
Step 2: Apply it to this jar.
Here the jar's height is exactly filled by the three balls, so together they occupy $\frac{2}{3}$ of the jar's volume, leaving $\frac{1}{3}$ as air.
Step 3: Compute the jar's volume and take one-third.
$V_{\text{cylinder}}=\pi r^2(6r)=6\pi r^3$, so $V_{\text{air}}=\frac13\times6\pi r^3=2\pi r^3$, matching option (A).
\[ \boxed{2\pi r^3} \]