Step 1: Clear fractions and try eliminating x.
Multiplying the first equation by 4 gives $2x + \frac{4}{3}y = 20$.
Step 2: Subtract this from the second equation.
\[ (2x + ky) - \left(2x + \frac{4}{3}y\right) = 7 - 20 \]
\[ \left(k - \frac{4}{3}\right)y = -13 \]
Step 3: Force the y-term to vanish for no solution to exist.
If $k - \frac{4}{3} \neq 0$, we could solve uniquely for $y$, so the system would be consistent. For the system to be inconsistent (no solution), this coefficient must be zero:
\[ k = \frac{4}{3} \]
\[ \boxed{k = \frac{4}{3}} \]