Step 1: Write as a single sine:
$\sin\theta - \sqrt3\cos\theta = 2\sin\left(\theta - \frac\pi3\right)$.
Step 2: Set to zero:
$\sin(\theta - \frac\pi3) = 0$ gives $\theta - \frac\pi3 = n\pi$. In $(0,\frac\pi2)$ the only solution is $n=0$, so $\theta = \frac\pi3$.
Step 3: Check the other options:
At $\frac\pi6$ the expression is $\frac12 - \frac32 = -1$. At $\frac\pi4$ it is $\frac{1-\sqrt3}{\sqrt2}$, nonzero. At $\frac\pi2$ it is $1$. Only $\frac\pi3$ gives zero.
Final Answer:
Option (A).
\[ \boxed{\theta=\frac{\pi}{3} \text{ (A)}} \]