Einstein’s photoelectric equation is:
\[ K_{\text{max}} = h (u - u_0) \]
Where \( K_{\text{max}} \) represents the maximum kinetic energy of the photoelectrons.
The relationship between the kinetic energy of the photoelectrons and the cut-off potential \( V_{\text{cut-off}} \) is:
\[ K_{\text{max}} = eV_{\text{cut-off}} \]
Equating these two expressions yields:
\[ eV_{\text{cut-off}} = h (u - u_0) \]
Rearranging to solve for the cut-off potential:
\[ V_{\text{cut-off}} = \frac{h (u - u_0)}{e} \]
Using the given constants and frequencies: \( h = 6.63 \times 10^{-34} \, \text{J} \cdot \text{s} \), \( e = 1.6 \times 10^{-19} \, \text{C} \), \( u = 6.8 \times 10^{14} \, \text{Hz} \), and \( u_0 = 3.6 \times 10^{14} \, \text{Hz} \):
\[ V_{\text{cut-off}} = \frac{(6.63 \times 10^{-34}) \times (6.8 \times 10^{14} - 3.6 \times 10^{14})}{1.6 \times 10^{-19}} \]
\[ V_{\text{cut-off}} = \frac{6.63 \times 10^{-34} \times 3.2 \times 10^{14}}{1.6 \times 10^{-19}} \]
\[ V_{\text{cut-off}} = \frac{2.12 \times 10^{-19}}{1.6 \times 10^{-19}} = 1.33 \, \text{V} \]
The calculated cut-off potential for the photoelectrons is \( 1.33 \, \text{V} \).