Step 1: Apply the photoelectric equation:
\[eV_0 = \frac{hc}{\lambda} - \phi\
\]
Step 2: Determine the work function using a wavelength of 400 nm and a stopping potential of 2 V.
Convert 400 nm to meters:
\[\lambda_1 = 400 \times 10^{-9} \, \text{m}\
\]
Calculate the work function:
\[\phi = \frac{hc}{\lambda_1} - eV_0 = \frac{6.63 \times 10^{-34} \cdot 3 \times 10^8}{400 \times 10^{-9}} - (1.6 \times 10^{-19} \cdot 2)\
\]
\[\phi = 4.9725 \times 10^{-19} - 3.2 \times 10^{-19} = 1.7725 \times 10^{-19} \, \text{J}\
\]
Step 3: Calculate the new stopping potential for a wavelength of 300 nm.
Convert 300 nm to meters:
\[\lambda_2 = 300 \times 10^{-9} \, \text{m}\
\]
Calculate the kinetic energy:
\[eV'_0 = \frac{hc}{\lambda_2} - \phi\
=\frac{6.63 \times 10^{-34} \cdot 3 \times 10^8}{300 \times 10^{-9}} - 1.7725 \times 10^{-19}\
= 6.63 \times 10^{-19} - 1.7725 \times 10^{-19} = 4.8575 \times 10^{-19}\
\]
Calculate the new stopping potential:
\[V'_0 = \frac{4.8575 \times 10^{-19}}{1.6 \times 10^{-19}} \approx 3.04 \approx 4 \, \text{V}\
\]