The question's phrasing is suboptimal. Nitrogen constitutes approximately 78% of the atmosphere, followed by Oxygen at 21% and Argon at 0.9%. The provided options are all trace gases.
Carbon dioxide ($CO_2$): \(\sim\)420 ppm (0.042%)
Carbon monoxide (CO): Variable, around 0.1 ppm
Propane ($C_3H_8$) and Butane ($C_4H_{10}$): Extremely low concentrations, at sub-ppb levels.
Among the available choices, Carbon dioxide has the highest concentration.