Question:medium

The percentage weight of Zn in white vitriol $[ZnSO_4 . 7H_2O]$ is approximately equal to $(at. \, mass\, of \, Zn= 65, S=32, 0=16 \, and \, H= 1)$

Updated On: May 22, 2026
  • $33.65%$
  • $32.56%$
  • $23.65%$
  • $22.65%$
Show Solution

The Correct Option is D

Solution and Explanation

To calculate the percentage weight of Zinc (Zn) in white vitriol, which is the compound [ZnSO_4 . 7H_2O], we first need to determine the molar mass of the entire compound.

  1. Calculate the molar mass of each component:
    • Zinc (Zn): Atomic mass = 65
    • Sulfur (S): Atomic mass = 32
    • Oxygen (O): Atomic mass = 16
    • Hydrogen (H): Atomic mass = 1
  2. Calculate the molar mass of ZnSO_4:
    • Molar mass of ZnSO_4 = (Zn) + (S) + (4 × O) = 65 + 32 + (4 × 16) = 161
  3. Calculate the molar mass of 7H_2O:
    • Molar mass of H_2O = (2 × H) + (O) = 2 × 1 + 16 = 18
    • Molar mass of 7H_2O = 7 × 18 = 126
  4. Calculate the total molar mass of [ZnSO_4 . 7H_2O]:
    • Total molar mass = Molar mass of ZnSO_4 + Molar mass of 7H_2O = 161 + 126 = 287
  5. Calculate the percentage weight of Zn in the compound:
    • Percentage weight of Zn = \(\frac{{\text{Molar mass of Zn}}}{{\text{Total molar mass of } [ZnSO_4 . 7H_2O]}} \times 100 = \frac{65}{287} \times 100 \approx 22.65\%\)

Therefore, the percentage weight of Zinc in white vitriol is approximately 22.65\%.

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