Step 1: Understanding the Question:
The question asks about the ion-exchange mechanism in the permutit process for water softening, specifically which ions are removed from hard water.
Step 2: Key Formula or Approach (Alternate):
Think of permutit as a sodium-rich zeolite (Na₂Z) that swaps its Na⁺ ions for the hardness-causing divalent cations. The zeolite framework has a stronger attraction for divalent ions over monovalent ones.
Step 3: Detailed Explanation:
Hard water contains Ca²⁺ and Mg²⁺ ions from dissolved salts like chlorides and sulfates. When passed through permutit (sodium aluminum silicate), the Ca²⁺ and Mg²⁺ displace Na⁺ from the zeolite matrix due to higher charge density and stronger electrostatic attraction. The reactions are: Ca²⁺ + Na₂Z → CaZ + 2Na⁺ and Mg²⁺ + Na₂Z → MgZ + 2Na⁺. The outgoing water now contains harmless Na⁺ instead of hardness ions. Once the zeolite is exhausted (all Na⁺ replaced), it is regenerated by flushing with concentrated brine (NaCl solution), reversing the exchange.
Step 4: Final Answer:
Na⁺ ions from permutit are exchanged with Ca²⁺ and Mg²⁺ ions present in hard water.