To determine which method cannot be used for the preparation of copper salts, we should evaluate the reaction of acids with different substances and how they form salts. Let's examine each option:
From the explanation above, it is clear that option 3, the action of acid on metals, cannot be used for the preparation of copper salts. This is because copper is not reactive enough to undergo a displacement reaction with dilute acids under normal conditions to form copper salts.
Therefore, the correct answer is option 3 (Action of acid on metals).
Study the reaction scheme shown below and identify the reactants A, B and C. 
Study the reaction given below and answer the questions that follow:
NaNO₃ + H₂SO₄ → NaHSO₄ + HNO₃ (below 200°C)
(a) Give one reason for maintaining the temperature below 200°C.
(b) Why is concentrated Sulphuric acid used in the above reaction?