Question:medium

The major product of the following reaction is:

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For alcohol dehydration with H$_2$SO$_4$, always check for carbocation stability, possible rearrangements, and apply Zaitsev's rule to predict the major product.
Updated On: Jun 19, 2026
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The Correct Option is A

Solution and Explanation

Step 1: Recognize the transformation.
Treating an alcohol with concentrated H₂SO₄ and heat signifies an acid-promoted dehydration process.

Step 2: Assess carbocation stability.

The starting alcohol is secondary, so loss of water generates a secondary carbocation initially.

Step 3: Check for structural rearrangement.

Examine possible hydride or alkyl migrations; a shift can produce a more stable tertiary carbocation, which becomes the dominant intermediate.

Step 4: Apply Zaitsev's guideline.

Elimination preferentially yields the alkene with greater substitution at the double bond, forming adjacent to the carbocation center.

Step 5: Depict the principal product.

After rearrangement and elimination, the most highly substituted alkene emerges as the major product.

Step 6: Stereochemistry note.

Stereochemical details are not relevant here, so the chief product is simply the Zaitsev alkene.
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