To solve this problem, we need to understand the geometrical arrangement of the vectors and how vector addition works.
Given:
The vector equation $\overrightarrow{A} + \overrightarrow{B} = \overrightarrow{C}$ implies that vectors $ \overrightarrow{A} $, $ \overrightarrow{B} $, and $ \overrightarrow{C} $ form a right triangle with $ \overrightarrow{C} $ as the hypotenuse.
In a right-angled triangle formed by vectors, the relation according to the Pythagorean theorem is:
$$|\overrightarrow{C}|^2 = |\overrightarrow{A}|^2 + |\overrightarrow{B}|^2.$$Substituting the given magnitudes:
This confirms that the angle between $ \overrightarrow{A} $ and $ \overrightarrow{B} $, denoted by $ \theta $, is $\pi/2$ (90 degrees), which represents a right angle.
Therefore, the angle between $ \overrightarrow{A} $ and $ \overrightarrow{B} $ is $\pi/2$.
Justification for incorrect options:
Hence, the correct option is $\pi/2$.