Question:medium

The IUPAC name of the following hydrocarbon is:

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Always select the longest carbon chain first, even if it is not drawn horizontally.
Updated On: Jun 9, 2026
  • 2, 5, 6-Trimethyloctane
  • 2-Ethyl-3,6-dimethylheptane
  • 3, 4, 7-Trimethyloctane
  • 2-Ethyl-2,6-dimethylheptane
Show Solution

The Correct Option is A

Solution and Explanation

Step 1: Recall the naming rules.
To name an alkane we find the longest continuous carbon chain, number it so substituents get the lowest set of locants, and list substituents alphabetically.
Step 2: Find the parent chain.
The longest chain in this hydrocarbon contains $8$ carbons, so the parent is octane.
Step 3: Place the branches.
There are three methyl branches on this octane chain. We must number to keep their positions as small as possible.
Step 4: Choose the numbering direction.
Numbering from one end gives methyls at $2, 5, 6$; numbering from the other end gives $3, 4, 7$. Comparing the sets, $\{2,5,6\}$ is lower at the first point of difference.
Step 5: Write the substituent prefix.
Three identical methyls give the prefix trimethyl, located at $2, 5, 6$.
Step 6: Assemble the name.
Combining, the IUPAC name is 2, 5, 6-Trimethyloctane, which is option 1.
\[ \boxed{2, 5, 6\text{-Trimethyloctane}} \]
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