Step 1: Use tangent form
With $t = \tan\theta$, $\cot2\theta = \frac{1-t^2}{2t}$, so the equation is $\frac1t\cdot\frac{1-t^2}{2t} = 1$.
Step 2: Solve for t
$1-t^2 = 2t^2$ gives $t^2 = \frac13$, so $\tan\theta = \pm\frac{1}{\sqrt3}$.
Step 3: General solution
$\tan^2\theta = \tan^2\frac{\pi}{6}$ gives $\theta = n\pi\pm\frac{\pi}{6}$, option (A).
Final Answer:
Option A.
\[ \boxed{\text{(A)}\ \theta = n\pi\pm\frac{\pi}{6}} \]