Step 1: Rock phosphate is a naturally occurring apatite mineral, not a refined salt. Step 2: Options 1 and 2 are acid-treated, soluble fertiliser forms, not the raw mineral. Step 3: \( \text{Ca}_3(\text{PO}_4)_2 \) alone ignores the hydroxide component of the natural apatite lattice. Step 4: The correct answer is \[ \boxed{3(\text{Ca}_3(\text{PO}_4)_2)\cdot\text{Ca(OH)}_2} \]