Question:medium

The eutectic point in the \(SiO_2-Na_2O\) phase diagram occurs at

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A eutectic point is the lowest melting temperature point in a binary phase diagram.
  • \(1200^\circ C\)
  • \(1590^\circ C\)
  • \(1390^\circ C\)
  • \(790^\circ C\)
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The Correct Option is D

Solution and Explanation

Step 1: Understanding the Question:
The question asks for the temperature of a specific invariant point (the eutectic) in the binary phase diagram of Silica ($SiO_2$) and Sodium Oxide ($Na_2O$).
Step 2: Detailed Explanation:

Eutectic Point: This is the composition and temperature at which a liquid phase transforms into two solid phases simultaneously upon cooling. It represents the lowest melting point for a mixture.

In the $Na_2O$-$SiO_2$ system, adding $Na_2O$ (a network modifier or flux) to $SiO_2$ significantly lowers its melting point from over $1700^{\circ}C$.

There are multiple compounds in this system. A prominent eutectic between sodium disilicate ($Na_2Si_2O_5$) and silica ($SiO_2$) occurs at approximately **$790^{\circ}C$ to $800^{\circ}C$**.

This low eutectic temperature is precisely why sodium carbonate (which decomposes to $Na_2O$) is used in glassmaking; it allows the silica to melt at much lower temperatures, saving energy.

Step 3: Final Answer:
The eutectic temperature in the $SiO_2$-$Na_2O$ system is $790^{\circ}C$.
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