Step 1: Use Gauss's law on the surface.
On the surface of a uniformly charged sphere the field behaves as if all the charge sat at the centre, so $E = \dfrac{1}{4\pi\varepsilon_0}\dfrac{q}{r^2}$. We just need $q$ in terms of $\rho$.
Step 2: Express the total charge.
Charge equals density times volume: $q = \rho \cdot \dfrac{4}{3}\pi r^3$.
Step 3: Substitute into the field expression.
$E = \dfrac{1}{4\pi\varepsilon_0}\cdot\dfrac{\rho\,\tfrac{4}{3}\pi r^3}{r^2}$.
Step 4: Cancel the $4\pi$ factors.
The $4\pi$ in the denominator cancels with the $4\pi$ from the volume, leaving $E = \dfrac{\rho}{3\varepsilon_0}\cdot\dfrac{r^3}{r^2}$.
Step 5: Simplify the radius powers.
$\dfrac{r^3}{r^2} = r$, so $E = \dfrac{\rho r}{3\varepsilon_0}$.
Step 6: Conclude.
The surface field is $\dfrac{\rho r}{3\varepsilon_0}$. \[ \boxed{E = \frac{\rho r}{3\varepsilon_0}} \]