Step 1: Know the charge spread.
A solid sphere of radius $R$ carries charge spread evenly through its whole volume. The volume charge density is $\rho$, meaning each unit of volume holds $\rho$ of charge.
Step 2: Find the total charge.
The volume of a sphere is $\dfrac{4}{3}\pi R^3$. So the total charge is $Q = \rho\cdot\dfrac{4}{3}\pi R^3$.
Step 3: Pick a Gaussian surface.
To find the field on the surface, imagine a sphere of radius $R$ around the charge. By symmetry the field points straight out and has the same size everywhere on this surface.
Step 4: Apply Gauss's law.
Gauss's law says the field times the surface area equals the enclosed charge divided by $\epsilon_0$. \[ E\,(4\pi R^2) = \frac{Q}{\epsilon_0} \]
Step 5: Put in the charge.
Replace $Q$ with our value: $E\,(4\pi R^2) = \dfrac{\rho\cdot\frac{4}{3}\pi R^3}{\epsilon_0}$.
Step 6: Solve for the field.
Divide both sides by $4\pi R^2$. The $4\pi$ cancels and one $R$ remains, giving $E = \dfrac{\rho R}{3\epsilon_0}$. \[ \boxed{\dfrac{\rho R}{3\epsilon_0}} \]