Question:medium

The correct order of melting points of the following salts is: 
LiCl & (I) 
LiF & (II) 
LiBr & (III) 
 

Show Hint

The melting point of ionic compounds decreases as the anion size increases because larger anions lead to weaker lattice energy.
Updated On: Jan 13, 2026
  • \(I>II>III\)
  • \(II>I>III\)
  • \(III>II>I\)
  • \(II>III>I\)
Show Solution

The Correct Option is B

Solution and Explanation

Step 1: Ionic Compound Melting Point Determinants
Melting point is governed by: 1. Lattice Energy: Greater lattice energy correlates with a higher melting point. 2. Anion Size: Smaller anions result in increased lattice energy.
Step 2: Salt Analysis 
Anion size order: Fluoride (F$^-$)<Chloride (Cl$^-$)<Bromide (Br$^-$). 
Lattice energy order: \[ LiF>LiCl>LiBr \] Melting point follows lattice energy: \[ LiF>LiCl>LiBr \] 
Step 3: Conclusion 
Therefore, the melting point order is: \[ {\(LiF (II)>LiCl (I)>LiBr (III)\)} \] This corresponds to option (B).

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