Step 1: Recall periodic trends for atomic radius.
Across a period (left to right): radius decreases due to increasing Zeff, so N>O and P>S. Down a group (top to bottom): radius increases due to added shells, so P,S>N,O.
Step 2: Arrange by combining trends.
Smallest: O (rightmost in 2nd period), then N (left of O in 2nd), then S (right of P in 3rd), then P (leftmost in 3rd). Complete order: O<N<S<P.
Step 3: Final Answer:
O<N<S<P (option 3).