The Gibbs–Duhem equation establishes the interdependence of chemical potentials in a mixture. It dictates that a change in one component's chemical potential necessitates compensatory changes in others to maintain a balance relative to the system's total molar Gibbs energy. This principle is fundamental to the thermodynamics of systems with multiple components. Therefore, the correct selection is (2).
Final Answer:
\[
\boxed{\text{(2) Gibbs–Duhem Equation}}
\]