Step 1: Use a right triangle
Edge $=1$, face diagonal $=\sqrt2$, space diagonal $=\sqrt3$. The edge and face diagonal are perpendicular.
Step 2: Read the tangent
In the right triangle with the edge adjacent to $\theta$ and the face diagonal opposite, $\tan\theta=\sqrt2/1$. Option (D).
Final Answer:
The angle is $\tan^{-1}\sqrt2$, option (D).
\[ \boxed{\tan^{-1}\sqrt2} \]