Step 1: Look at copper.
Copper is a metal. Cooling it calms the lattice vibrations, so electrons flow more freely and the resistivity drops.
Step 2: Look at silicon.
Silicon is a semiconductor. Cooling it leaves fewer free charge carriers, so the resistivity rises.
Step 3: Combine.
So on cooling, copper's resistivity decreases while silicon's increases. \[ \boxed{\text{decreases in copper, increases in silicon}} \]