Step 1: Fix the one association you are most sure of first.
The shortwave infrared (S) band is universally associated with water absorption features of the leaf, so $(S)$-$(i)$ must hold.
Step 2: Eliminate options that violate this.
Option (C) pairs $(S)$-$(ii)$ and option (D) pairs $(S)$-$(ii)$ as well, both wrong, so options (C) and (D) are eliminated, leaving only options (A) and (B).
Step 3: Distinguish (A) from (B) using the Green/Red pair.
Option (A) has $(P)$ Green $\to (iv)$ reflectance from chlorophyll and $(Q)$ Red $\to (iii)$ absorption from chlorophyll. Option (B) swaps these.
Step 4: Decide which pairing is physically correct.
Chlorophyll absorbs red light strongly (hence low red reflectance, an absorption feature) and absorbs green light only weakly (hence the green reflectance peak that makes leaves look green). This matches option (A)'s pairing, not option (B)'s.
Step 5: Conclude.
Option (A) is the only one consistent with both the SWIR-water rule and the correct Green/Red chlorophyll behavior. \[ \boxed{\text{Option (A)}} \]