Provided data:
The relative velocity of Ravi and Ashok when approaching each other is the sum of their individual velocities:
\[ \text{Combined Velocity} = \frac{125}{9} + \frac{100}{9} = 25 \, \text{m/s} \]
The time until they meet is determined by the distance and their combined velocity:
\[ \text{Time} = \frac{\text{Distance}}{\text{Relative Velocity}} = \frac{225}{25} = 9 \, \text{seconds} \]
In 9 seconds, Ravi covers the following distance:
\[ \text{Distance} = \frac{100}{9} \times 9 = 100 \, \text{meters} \]
Vijay begins 54 meters behind Ravi. Consequently, Vijay must cover a total distance of:
\[ \text{Distance} = 100 + 54 = 154 \, \text{meters} \]
Vijay's velocity is calculated as:
\[ \text{Velocity} = \frac{154}{9} \, \text{m/s} \]
The conversion of Vijay's velocity to kilometers per hour is as follows:
\[ \text{Velocity} = \frac{154}{9} \times \frac{18}{5} = \frac{308}{5} = 61.6 \, \text{km/h} \]
Therefore, Vijay's velocity is \( \textbf{61.6 km/h} \).
The correct option is \( \textbf{(C): 61.6} \).