Question:medium

Pure $Si$ at $500\, K$ has equal number of electron $(n_e)$ and hole $(n_h)$ concentrations of $1.5 \times 10^{16}\, m^{-3}$ Doping by indium increases $n_h$ to 4.5 $\times 10^{22}\, m^{-3}$ The doped semiconductor is of

Updated On: May 26, 2026
  • p-type having electron concentration $n_e=5\times 10^9\, m^{-3}$
  • n-type with electron concentration $n_e=5\times 10^{22} \,m^{-3}$
  • p-type with electron concentration $n_e=2.5\times 10^{10}\, m^{-3}$
  • n-type with electron concentration $n_e=2.5\times 10^{23}\, m^{-3}$
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The Correct Option is A

Solution and Explanation

The problem states that pure silicon (\(Si\)) at 500 K has equal electron (\(n_e\)) and hole (\(n_h\)) concentrations of \(1.5 \times 10^{16}\, \text{m}^{-3}\). After doping with indium, the hole concentration increases to \(4.5 \times 10^{22} \, \text{m}^{-3}\). The task is to determine the type of semiconductor and the concentration of electrons.

Step 1: Understanding Semiconductor Doping

  • In semiconductors, doping introduces additional charge carriers. P-type semiconductors have an excess of holes, while n-type semiconductors have an excess of electrons.
  • Indium, being a Group III element, is a p-type dopant. It increases the number of holes in the semiconductor.

Step 2: Applying the Mass Action Law

  • For intrinsic semiconductors, the product of electron and hole concentrations remains constant and equal to the square of the intrinsic carrier concentration (\(n_i\)): n_i^2 = n_e \cdot n_h.
  • Given that initially \(n_e = n_h = 1.5 \times 10^{16}\, \text{m}^{-3}\), we calculate: n_i^2 = (1.5 \times 10^{16})^2 = 2.25 \times 10^{32}\, \text{m}^{-6}.

Step 3: Calculating Electron Concentration in Doped Semiconductor

  • After indium doping, the hole concentration becomes \(n_h = 4.5 \times 10^{22}\, \text{m}^{-3}\).
  • Using the mass action law: n_e = \frac{n_i^2}{n_h} = \frac{2.25 \times 10^{32}}{4.5 \times 10^{22}} = 5 \times 10^{9}\, \text{m}^{-3}.

Step 4: Determining Type of Semiconductor

  • The significantly higher hole concentration (\(n_h\)) compared to electron concentration (\(n_e\)) confirms it as a p-type semiconductor.

Conclusion: The doped semiconductor is p-type with an electron concentration of \(n_e = 5 \times 10^9\, \text{m}^{-3}\).

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