The problem states that pure silicon (\(Si\)) at 500 K has equal electron (\(n_e\)) and hole (\(n_h\)) concentrations of \(1.5 \times 10^{16}\, \text{m}^{-3}\). After doping with indium, the hole concentration increases to \(4.5 \times 10^{22} \, \text{m}^{-3}\). The task is to determine the type of semiconductor and the concentration of electrons.
Step 1: Understanding Semiconductor Doping
- In semiconductors, doping introduces additional charge carriers. P-type semiconductors have an excess of holes, while n-type semiconductors have an excess of electrons.
- Indium, being a Group III element, is a p-type dopant. It increases the number of holes in the semiconductor.
Step 2: Applying the Mass Action Law
- For intrinsic semiconductors, the product of electron and hole concentrations remains constant and equal to the square of the intrinsic carrier concentration (\(n_i\)):
n_i^2 = n_e \cdot n_h.
- Given that initially \(n_e = n_h = 1.5 \times 10^{16}\, \text{m}^{-3}\), we calculate:
n_i^2 = (1.5 \times 10^{16})^2 = 2.25 \times 10^{32}\, \text{m}^{-6}.
Step 3: Calculating Electron Concentration in Doped Semiconductor
- After indium doping, the hole concentration becomes \(n_h = 4.5 \times 10^{22}\, \text{m}^{-3}\).
- Using the mass action law:
n_e = \frac{n_i^2}{n_h} = \frac{2.25 \times 10^{32}}{4.5 \times 10^{22}} = 5 \times 10^{9}\, \text{m}^{-3}.
Step 4: Determining Type of Semiconductor
- The significantly higher hole concentration (\(n_h\)) compared to electron concentration (\(n_e\)) confirms it as a p-type semiconductor.
Conclusion: The doped semiconductor is p-type with an electron concentration of \(n_e = 5 \times 10^9\, \text{m}^{-3}\).