Step 1: Temperatures
$T_A\propto9pV$, $T_B\propto3pV$, $T_C\propto pV$, $T_D\propto9pV$.
Step 2: Check each option
A to B and B to C lose temperature, so their internal energy decreases and the statements are wrong. D to A has no change in internal energy.
Step 3: C to D
Temperature rises from $pV$ to $9pV$ at constant pressure, so energy increases and heat must be supplied.
Final Answer:
The statement about C to D is correct.
\[ \boxed{\text{(C) }\text{for process C to D, heat is gained and internal energy increases}} \]