Question:medium

Oil of wintergreen is chemically known as:

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Oil of wintergreen = Methyl salicylate = ester of salicylic acid + methanol. It is commonly used in muscle pain relief balms and has a strong mint-like smell.
Updated On: May 29, 2026
  • Methyl acetate
  • Methyl salicylate
  • Ethyl salicylate
  • Salicylic acid
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The Correct Option is B

Solution and Explanation

Step 1 : Understanding the Question:
The question asks for the formal chemical name of a common naturally occurring aromatic compound known as "Oil of Wintergreen." This is an organic chemistry question that links common trivial names with systematic IUPAC nomenclature. Oil of wintergreen is famous for its minty aroma and its medicinal use as a counter-irritant for muscle and joint pain.
Step 2 : Key Formulas and approach:
To solve this, we must identify the chemical class of the compound. Oil of wintergreen is an ester. Esters are formed by the reaction of an alcohol and a carboxylic acid. By knowing the components used to synthesize this compound, we can determine its systematic name.
The approach is:
1. Identify the parent acid (salicylic acid).
2. Identify the parent alcohol (methanol).
3. Apply ester nomenclature rules: (alkyl group from alcohol) + (acid name ending in -ate).
Step 3 : Detailed Explanation:

Oil of wintergreen is the primary constituent found in the wintergreen plant (Gaultheria procumbens).

Chemically, it is synthesized via the esterification of Salicylic acid with Methyl alcohol (Methanol).

Reaction: $C_6H_4(OH)COOH + CH_3OH \rightarrow C_6H_4(OH)COOCH_3 + H_2O$.

The resulting molecule consists of a benzene ring with an ortho-hydroxyl group and a methyl ester group.

Following nomenclature, "Methyl" comes from the methanol, and "Salicylate" comes from the salicylic acid.

Methyl acetate is the ester of acetic acid, which has a fruity smell and is unrelated.

Ethyl salicylate would require ethanol, which is not the naturally occurring form in wintergreen.

Salicylic acid itself is a solid precursor and does not have the oily liquid properties or the characteristic scent.

Step 4 : Final Answer:
The chemical name for Oil of Wintergreen is Methyl salicylate.
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